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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">novtexmech</journal-id><journal-title-group><journal-title xml:lang="ru">Мехатроника, автоматизация, управление</journal-title><trans-title-group xml:lang="en"><trans-title>Mekhatronika, Avtomatizatsiya, Upravlenie</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1684-6427</issn><issn pub-type="epub">2619-1253</issn><publisher><publisher-name>Commercial Publisher «New Technologies»</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17587/mau.27.429-438</article-id><article-id custom-type="elpub" pub-id-type="custom">novtexmech-2072</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>АВТОМАТИЗАЦИЯ И УПРАВЛЕНИЕ ТЕХНОЛОГИЧЕСКИМИ ПРОЦЕССАМИ И ПРОИЗВОДСТВАМИ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>AUTOMATION AND CONTROL TECHNOLOGICAL PROCESSES</subject></subj-group></article-categories><title-group><article-title>Методы и алгоритмы автоматизации управления технологическим процессом формирования композиционных покрытий</article-title><trans-title-group xml:lang="en"><trans-title>Methods and Algorithms for Automation of Process Control in the Formation of Composite Coatings</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Ганигин</surname><given-names>С. Ю.</given-names></name><name name-style="western" xml:lang="en"><surname>Ganigin</surname><given-names>S. Yu.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р техн. наук, доц., зав. каф. </p><p>Самара</p></bio><bio xml:lang="en"><p>Samara, 443100 </p></bio><email xlink:type="simple">ganigin.s.yu@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Киященко</surname><given-names>В. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Kiyashchenko</surname><given-names>V. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>мл. науч. сотр. </p><p>Самара</p></bio><bio xml:lang="en"><p>Kiyashchenko V. V., Junior Researcher, </p><p>Samara, 443100 </p></bio><email xlink:type="simple">vv.kiyashchenko@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кирсанов</surname><given-names>А. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Kirsanov</surname><given-names>A. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. техн. наук, зав. каф. </p><p>Москва</p></bio><bio xml:lang="en"><p>Moscow, 107028 </p></bio><email xlink:type="simple">kas792@yandex.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Миронов</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Mironov</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>аспирант </p><p>Москва</p></bio><bio xml:lang="en"><p>Moscow, 107028 </p></bio><email xlink:type="simple">artur.mironov3@gmail.com</email><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Самарский государственный технический университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Samara State Technical University</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Московский Политех</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Moscow Polytech</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2026</year></pub-date><pub-date pub-type="epub"><day>19</day><month>08</month><year>2026</year></pub-date><volume>27</volume><issue>8</issue><fpage>429</fpage><lpage>438</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Commercial Publisher «New Technologies», 2026</copyright-statement><copyright-year>2026</copyright-year><copyright-holder xml:lang="ru">Commercial Publisher «New Technologies»</copyright-holder><copyright-holder xml:lang="en">Commercial Publisher «New Technologies»</copyright-holder><license xlink:href="https://mech.novtex.ru/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://mech.novtex.ru/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://mech.novtex.ru/jour/article/view/2072">https://mech.novtex.ru/jour/article/view/2072</self-uri><abstract><p>Представлена методика автоматизации управления процессом детонационно-газового напыления (ДГН) реакционноспособных композиционных покрытий системы Ni/Al на основе системы поддержки принятия решений (СППР) и цифрового двойника технологического процесса. Разработанная архитектура включает уровни низкоуровневого контроля с программируемым логическим контроллером, стабилизации параметров струи по данным диагностического комплекса, предиктивного регулирования качества и оптимизационного контура, реализующего многокритериальную адаптацию режимов напыления.В качестве выходных переменных модели использовались структурные метрики, полученные методом морфометрического анализа изображений электронной микроскопии: средняя площадь пор, число нерасплавленных частиц, удельная длина межфазных границ и доля предварительно образованных интерметаллидных фаз. Для описания взаимосвязей между технологическими параметрами (степень наполнения, соотношение газов, дистанция напыления, расход порошка, температура и давление газа) и структурными характеристиками применена методология поверхности отклика (RSM) с квадратичными регрессионными моделями. Дисперсионный анализ (ANOVA) подтвердил статистическую значимость факторов и адекватность моделей.Результаты численного моделирования и верификации показали, что температура газового потока и дистанция напыления оказывают наибольшее влияние на формирование межфазных границ. Оптимизация параметров методом желательности Харрингтона и с использованием генетического алгоритма позволила минимизировать пористость и число нерасплавленных частиц, одновременно максимизируя длину границ. Средняя ошибка прогноза по всем метрикам не превышает 5...8 %.Разработанная СППР обеспечивает адаптивный выбор и корректировку режимов ДГН, сокращает объем экспериментальных испытаний и обеспечивает воспроизводимость структуры покрытия. Методика может быть интегрирована в интеллектуальные системы автоматического управления и платформы цифровых двойников технологических процессов, а дальнейшее развитие связано с применением машинного обучения и гибридных физико-статистических моделей.</p></abstract><trans-abstract xml:lang="en"><p>A methodology for intelligent control of the detonation-gas spraying (DGS) process of reactive Ni/Al composite coatings is presented, based on a Decision Support System (DSS) integrated with a digital twin of the technological process. The proposed hierarchical control architecture includes PLC-based sequencing, real-time stabilization of jet parameters using diagnostic data, predictive quality regulation, and a multi-objective optimization loop ensuring adaptive adjustment of process modes. The coating responses were evaluated from SEM image analysis: average pore area, number of unmelted particles, specific length of interphase boundaries, and fraction of pre-formed intermetallic phases. The relationships between technological parameters (barrel filling degree, C2H2/O2 ratio, spray distance, powder feed rate, gas temperature, and pressure) and structural characteristics were described using the Response Surface Methodology (RSM) with second-order regression models. Analysis of variance (ANOVA) confirmed the statistical significance of the factors and the adequacy of the model. Simulation and experimental verification demonstrated that gas temperature and spray distance exert the strongest influence on the formation of interphase boundaries. Optimization using the Harrington desirability function combined with a genetic algorithm enabled minimization of porosity and unmelted particles, while maximizing specific length of interphase boundaries. The mean prediction error across all structural metrics did not exceed 5—8 %. The developed DSS provides adaptive control and automatic optimization of DGS parameters, significantly reducing experimental workload and improving the reproducibility of coating structures. The methodology is suitable for integration into intelligent control systems and digital twin platforms for thermal spraying processes. Future work will focus on applying machine-learning-driven hybrid models combining empirical and physicochemical simulations for enhanced prediction accuracy and autonomy.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>детонационное напыление</kwd><kwd>композиционные покрытия</kwd><kwd>СВС-реакция</kwd><kwd>система поддержки принятия решений</kwd><kwd>метод поверхности отклика</kwd></kwd-group><kwd-group xml:lang="en"><kwd>detonation spraying</kwd><kwd>composite coatings</kwd><kwd>SHS reaction</kwd><kwd>decision support system</kwd><kwd>response surface methodology</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The research was carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation within the framework of the state task (theme no 125040404855-0).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Sampath S., Ravi V. P., Sundararajan S. An Overview on Synthesis, Processing and Applications of Nickel Aluminides: From Fundamentals to Current Prospects // Crystals. 2024. Vol. 13(3). Art. 435. DOI: 10.3390/cryst13030435.</mixed-citation><mixed-citation xml:lang="en">Sampath S., Ravi V. P., Sundararajan S. An Overview on Synthesis, Processing and Applications of Nickel Aluminides: From Fundamentals to Current Prospects, Crystals, 2024, vol. 13(3), art. 435, DOI: 10.3390/cryst13030435.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Gao X., Martin S., Wen X., Tian Y., Zhang B., Wang Y., Chen Y., Qiao Sh., Wang F., Liu S., Yuan C. Thermodynamics and kinetics of interdiffusion in Ni//NiAl diffusion couples // Journal of Alloys and Compounds. 2024. Vol. 971. Art. 172751. DOI: 10.1016/j.jallcom.2023.172751.</mixed-citation><mixed-citation xml:lang="en">Gao X., Martin S., Wen X., Tian Y., Zhang B., Wang Y., Chen Y., Qiao Sh., Wang F., Liu S., Yuan C. Thermodynamics and kinetics of interdiffusion in Ni//NiAl diffusion couples, Journal of Alloys and Compounds, 2024, vol. 971, art. 172751, DOI: 10.1016/j.jallcom.2023.172751.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Filipek R., Danielewski M., Tyliszczak, E., Pawelkiewicz M., Datta S. Thermal Stability of NiAl-Base Coatings for High Temperature Application // Defect and Diffusion Forum. 2005. P. 709—714. DOI: 10.4028/www.scientific.net/DDF.237-240.709.</mixed-citation><mixed-citation xml:lang="en">Filipek R., Danielewski M., Tyliszczak, E., Pawelkiewicz M., Datta S. Thermal Stability of NiAl-Base Coatings for High Temperature Application, Defect and Diffusion Forum, 2005, pp. 709—714, DOI: 10.4028/www.scientific.net/DDF.237-240.709.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Ostovari Moghaddam A., Samodurova M., Mikhailov D., Trofimov E. High entropy intermetallic coatings fabricated by detonation spraying // Materials Letters. 2022. Vol. 311. Art. 131560. DOI: 10.1016/j.matlet.2021.131560.</mixed-citation><mixed-citation xml:lang="en">Ostovari Moghaddam A., Samodurova M., Mikhailov D., Trofimov E. High entropy intermetallic coatings fabricated by detonation spraying, Materials Letters, 2022, vol. 311, art. 131560. DOI: 10.1016/j.matlet.2021.131560.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Jia Q., Li D., Li S., Zhang Z., Zhang N. High-Temperature Oxidation Resistance of NiAl Intermetallic Formed In Situ by Thermal Spraying // Coatings. 2018. N. 8. Art. 292. DOI: 10.3390/coatings8080292.</mixed-citation><mixed-citation xml:lang="en">Jia Q., Li D., Li S., Zhang Z., Zhang N. High-Temperature Oxidation Resistance of NiAl Intermetallic Formed In Situ by Thermal Spraying, Coatings, 2018. no. 8, art. 292, DOI: 10.3390/coatings8080292.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Ostovari Moghaddam A., Shaburova N., Naseri M.,Latfulina Y., Samodurova M., Krymsky V., Litvinyuk K., Trofimov E. Detonation Spraying of Ni-Based Composite Coatings Reinforced by High-Entropy Intermetallic Particles // Metals. 2023. N. 13. Art. 1807. DOI: 10.3390/met13111807.</mixed-citation><mixed-citation xml:lang="en">Ostovari Moghaddam A., Shaburova N., Naseri M., Latfulina Y., Samodurova M., Krymsky V., Litvinyuk K., Trofimov E. Detonation Spraying of Ni-Based Composite Coatings Reinforced by High-Entropy Intermetallic Particles, Metals, 2023, no. 13, art. 1807, DOI: 10.3390/met13111807.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Kantay N., Rakhadilov B., Kurbanbekov S., Yeskermessov D., Yerbolatova G., Apsezhanova A. Influence of DetonationSpraying Parameters on the Phase Composition and Tribological Properties of Al2O3 Coatings // Coatings. 2021. N. 11. Art. 10. DOI: 10.3390/coatings11070793.</mixed-citation><mixed-citation xml:lang="en">Kantay N., Rakhadilov B., Kurbanbekov S., Yeskermessov D., Yerbolatova G., Apsezhanova A. Influence of DetonationSpraying Parameters on the Phase Composition and Tribological Properties of Al2O3 Coatings, Coatings, 2021, no. 11, art. 10, DOI: 10.3390/coatings11070793.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Dutta G., Gupta N., Fourer R. An optimization-based decision support system for strategic planning in a process industry: The case of aluminium company in India // Journal of the Operational Research Society. 2011. N. 62. P. 616—626. DOI: 10.1057/jors.2010.8.</mixed-citation><mixed-citation xml:lang="en">Dutta G., Gupta N., Fourer R. An optimization-based decision support system for strategic planning in a process industry: The case of aluminium company in India, Journal of the Operational Research Society, 2011, no. 62, pp. 616—626, DOI: 10.1057/jors.2010.8.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Malamousi K., Delibasis K., Allcock B., Kamnis S. Digital transformation of thermal and cold spray processes with emphasis on machine learning // Surface and Coatings Technology. 2022. N. 433. Art. 128138. DOI: 10.1016/j.surfcoat.2022.128138.</mixed-citation><mixed-citation xml:lang="en">Malamousi K., Delibasis K., Allcock B., Kamnis S. Digital transformation of thermal and cold spray processes with emphasis on machine learning, Surface and Coatings Technology, 2022, no. 433, art. 128138, DOI: 10.1016/j.surfcoat.2022.128138.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Kiener C., Schwarzer S., Zimmermann S. An Intelligent digital twins streamlines the production planning in context of custom 3D workpieces for powder coating // IEEE Access. 2025. Vol. 13. P. 35243—35253. DOI: 10.1109/ACCESS.2025.3544140.</mixed-citation><mixed-citation xml:lang="en">Kiener C., Schwarzer S., Zimmermann S. An Intelligent digital twins streamlines the production planning in context of custom 3D workpieces for powder coating, IEEE Access, 2025,/ vol. 13, pp. 35243—35253, DOI: 10.1109/ACCESS.2025.3544140.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Агарков А. А., Самборук А. Р., Нечаев И. В. Детонационно-газовое напыление композиционных покрытий tic-Fe и tic-Fe-AL2O3 // Современные материалы, техника и технологии. 2020. № 2(29). С. 4—9.</mixed-citation><mixed-citation xml:lang="en">Agarkov A. A., Samboruk A. R., Nechaev I. V. Detonation-Gas Spraying of Composite Coatings TIC-FE and TIC-FEAL2O3, Modern Materials, Equipment and Technologies, 2020, no. 2(29), pp. 4—9 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Ulianitsky V. Yu., Dudina D. V., Batraev I. S., Rybin D. K., Bulina N. V., Ukhina A. V., Bokhonov B. B. The influence of the in-situ formed and added carbon on the formation of metastable Ni-based phases during detonation spraying // Materials Letters. 2016. Vol. 181. P. 127—131. DOI: 10.1016/j.matlet.2016.06.022.</mixed-citation><mixed-citation xml:lang="en">Ulianitsky V. Yu., Dudina D. V., Batraev I. S., Rybin D. K., Bulina N. V., Ukhina A. V., Bokhonov B. B. The influence of the in-situ formed and added carbon on the formation of metastable Ni-based phases during detonation spraying, Materials Letters, 2016, vol. 181, pp. 127—131, DOI: 10.1016/j.matlet.2016.06.022.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Maulet M., Rakhadilov B. K., Wieleba W., Sagdoldina Zh. B. Utilizing detonation spraying in the process of fortifying components within power plant technology // Bulletin of Shakarim University. Technical Sciences. 2024. N. 1(13). P. 347—352. DOI: 10.53360/2788-7995-2024-1(13)-43.</mixed-citation><mixed-citation xml:lang="en">Maulet M., Rakhadilov B. K., Wieleba W., Sagdoldina Zh. B. Utilizing detonation spraying in the process of fortifying components within power plant technology, Bulletin of Shakarim University. Technical Sciences, 2024, no. 1 (13), pp. 347—352, DOI: 10.53360/2788-7995-2024-1(13)-43.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Li L., Wang L., Zhao L., Wang X. Microstructure and adhesion strength of NiAl coating prepared on Q235 substrate by combustion synthesis assisted with Cu-Zn interlayer // Surface and Coatings Technology. 2018. Vol. 344. P. 564—571. DOI: 10.1016/j.surfcoat.2018.03.076.</mixed-citation><mixed-citation xml:lang="en">Li L., Wang L., Zhao L., Wang X. Microstructure and adhesion strength of NiAl coating prepared on Q235 substrate by combustion synthesis assisted with Cu-Zn interlayer, Surface and Coatings Technology, 2018, vol. 344, pp. 564—571, DOI: 10.1016/j.surfcoat.2018.03.076.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Пантелеенко Ф. И., Жэн П. Прогрессивные технологии лазерной наплавки и газотермического напыления // Литье и металлургия. 2024. № 3. С. 61—65. DOI: 10.21122/1683-6065-2024-3-61-65.</mixed-citation><mixed-citation xml:lang="en">Panteleenko F. I., Zheng P. Progressive Technologies of Laser Surfacing and Gas-Thermal Spraying, Molding and Metallurgy, 2024, no. 3, pp. 61—65, DOI: 10.21122/1683-6065-2024-3-61-65 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Baizhan D., Sagdoldina Zh., Buitkenov D., Kambarov Y., Nabioldina A., Zhumabekova V., Bektasova G. Study of the Structural-Phase State of Hydroxyapatite Coatings Obtained by Detonation Spraying at Different O2/C2H2 Ratios // Crystals. 2023. N. 13. Art. 1564. DOI: 10.3390/cryst13111564.</mixed-citation><mixed-citation xml:lang="en">Baizhan D., Sagdoldina Zh., Buitkenov D., Kambarov Y., Nabioldina A., Zhumabekova V., Bektasova G. Study of the Structural-Phase State of Hydroxyapatite Coatings Obtained by Detonation Spraying at Different O2/C2H2 Ratios, Crystals, 2023, no. 13, art. 1564, DOI: 10.3390/cryst13111564.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Baizhan D., Sagdoldina Zh., Buitkenov D., Kot M., Zhurerova L. Influence of Detonation Spraying Parameters on the Microstructure and Mechanical Properties of Hydroxyapatite Coatings // Materials. 2024. N. 17. Art. 5390. DOI: 10.3390/ma17215390.</mixed-citation><mixed-citation xml:lang="en">Baizhan D., Sagdoldina Zh., Buitkenov D., Kot M., Zhurerova L. Influence of Detonation Spraying Parameters on the Microstructure and Mechanical Properties of Hydroxyapatite Coatings, Materials, 2024, no. 17, art. 5390, DOI: 10.3390/ma17215390.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Чижик С. А., Витязь П. А., Хейфец М. Л., Ивашко В. С., Харламов М. Ю., Харламов Ю. А. Моделирования процессов формирования, изнашивания и разрушения газотермических покрытий на различных структурных уровнях // Упрочняющие технологии и покрытия. 2022. Т. 18, № 4 (208). С. 184—192. DOI: 10.36652/1813-1336-2022-18-4-184-192.</mixed-citation><mixed-citation xml:lang="en">Chizhik S. A., Vityaz P. A., Heifets M. L., Ivashko V. S., Kharlamov M. Yu., Kharlamov Yu. A. Structural Levels of Process Modeling The Formation and Wear of High-Strength Thermal Spray Coatings, Hardening technologies and coatings, 2022, vol. 18, no. 4 (208), pp. 184-192.,DOI: 10.36652/1813-1336-2022-18-4-184-192 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Jurić D., Čatipović N., Peko I., Krolo J., Antunović K., Kunac K., Kljajo M., Oñate A., Tuninetti V. Multi-objective optimization of thermally sprayed CrNiMo coatings on titanium substrates: influence of spray distance and layer count on mechanical properties using desirability analysis // International conference "Mechanical Technologies and Structural Materials". 2025. P. 123—137.</mixed-citation><mixed-citation xml:lang="en">Jurić D., Čatipović N., Peko I., Krolo J., Antunović K., Kunac K., Kljajo M., Oñate A., Tuninetti V. Multi-objective optimization of thermally sprayed CrNiMo coatings on titanium substrates: influence of spray distance and layer count on mechanical properties using desirability analysis, International conference "Mechanical Technologies and Structural Materials", 2025, pp. 123—137.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Dudina D., Pribytkov G., Krinitcyn M., Korchagin M., Bulina N., Bokhonov B., Batraev I., Rybin D., Ulianitsky V. Detonation spraying behavior of TiCx-Ti powders and the role of reactive processes in the coating formation // Ceramics International. 2015. No. 40. P. 3253—3260. DOI: 10.1016/j.ceramint.2015.08.166.</mixed-citation><mixed-citation xml:lang="en">Dudina D., Pribytkov G., Krinitcyn M., Korchagin M., Bulina N., Bokhonov B., Batraev I., Rybin D., Ulianitsky V. Detonation spraying behavior of TiCx-Ti powders and the role of reactive processes in the coating formation, Ceramics International, 2015, no. 40, pp. 3253—3260, DOI: 10.1016/j.ceramint.2015.08.166.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Pichugin N., Pesterev E., Yakovlev E., Maznoy A. Improving high-temperature oxidation resistance of porous Ni-Al intermetallics obtained by self-propagating high-temperature synthesis through microalloying with Dy and Y // Journal of Alloys and Compounds. 2025. Vol. 1010. Art. 178057. DOI: 10.1016/j.jallcom.2024.178057.</mixed-citation><mixed-citation xml:lang="en">Pichugin N., Pesterev E., Yakovlev E., Maznoy A. Improving high-temperature oxidation resistance of porous Ni-Al intermetallics obtained by self-propagating high-temperature synthesis through microalloying with Dy and Y, Journal of Alloys and Compounds, 2025, vol. 1010, art. 178057, DOI:10.1016/j.jallcom.2024.178057.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Nikbakht R., Assadi H. Phase-field modelling of self-propagating high-temperature synthesis of NiAl // Acta Materialia. 2012. Vol. 60, N. 10. P. 4041—4053. DOI: 10.1016/j.actamat.2012.04.017.</mixed-citation><mixed-citation xml:lang="en">Nikbakht R., Assadi H. Phase-field modelling of self-propagating high-temperature synthesis of NiAl, Acta Materialia, 2012, vol. 60, no. 10, pp. 4041-4053, DOI: 10.1016/j.actamat.2012.04.017.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Mukhachev A., Yelatontsev D., Kharytonova O., Grechanyuk N. Production of Neutron-Absorbing Zirconium-Boron Alloy by Self-Propagating High-Temperature Synthesis and Its Refining via Electron Beam Melting // Alloys. 2024. N. 3. P. 232—245. DOI: 10.3390/alloys3030013.</mixed-citation><mixed-citation xml:lang="en">Mukhachev A., Yelatontsev D., Kharytonova O., Grechanyuk N. Production of Neutron-Absorbing Zirconium-Boron Alloy by Self-Propagating High-Temperature Synthesis and Its Refining via Electron Beam Melting, Alloys, 2024, no. 3, pp. 232—245, DOI: 10.3390/alloys3030013.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Толочко Б. П., Золотарев К. В. Исследование быстропротекающих твердофазных химических реакций в Сибирском центре синхротронного и терагерцового излучения // Журнал структурной химии. 2016. Т. 57, № 7. С. 1362—1388. DOI: 10.15372/JSC20160702.</mixed-citation><mixed-citation xml:lang="en">Tolochko B. P., Zolotarev K. V. Research On Fast SolidState Chemical Reactions At The Siberian Synchrotron And Terahertz Radiation Center, Journal of Structural Chemistry, 2016, vol. 57, no. 7, pp. 1362—1388, DOI: 10.15372/JSC20160702 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Lis J. Self-Propagating High-Temperature Synthesis // Encyclopedia of Materials: Technical Ceramics and Glasses. 2021. P. 40—58. DOI: 10.1016/B978-0-12-803581-8.12076-4.</mixed-citation><mixed-citation xml:lang="en">Lis J. Self-Propagating High-Temperature Synthesis, Encyclopedia of Materials: Technical Ceramics and Glasses, 2021, pp. 40—58, DOI: 10.1016/B978-0-12-803581-8.12076-4.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Ксандопуло Г. И. Модифицирующее воздействие сил вращения на механизм процессов во фронте волны самораспространяющегося высокотемпературного синтеза металлотермических систем при синтезе неорганических материалов // Горение и взрыв. 2021. Т. 14, № 1. С. 89—95. DOI: 10.30826/CE21140111.</mixed-citation><mixed-citation xml:lang="en">Ksandopulo G. I. Modifying Effect of Rotational Forces on the Mechanism of the Processes of the Self-Propagating HighTemperature Synthesis in Metallothermal Systems During the Synthesis of Inorganic Materials, Combustion and Explosion, 2021, vol. 14, no 1, pp. 89—95, DOI: 10.30826/CE21140111 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Ward D., Gupta A., Saraf S., Zhang C., Selvan Sakthivel T., Barkam S., Agarwal A., Seal S. Functional NiAl-graphene oxide composite as a model coating for aerospace component repair // Carbon. 2016. Vol. 105. P. 529—543. DOI: 10.1016/j.carbon.2016.04.025.</mixed-citation><mixed-citation xml:lang="en">Ward D., Gupta A., Saraf S., Zhang C., Selvan Sakthivel T., Barkam S., Agarwal A., Seal S. Functional NiAl-graphene oxide composite as a model coating for aerospace component repair, Carbon, 2016, vol. 105, pp. 529—543, DOI: 10.1016/j.carbon.2016.04.025.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Zeba N., Faheem J. Tuning plasma jet parameters for enhanced ceramic composite coatings: A comprehensive review of microstructure, performance, and applications // Next Materials. 2025. Vol. 9. 101206. DOI: 10.1016/j.nxmate.2025.101206.</mixed-citation><mixed-citation xml:lang="en">Zeba N., Faheem J. Tuning plasma jet parameters for enhanced ceramic composite coatings: A comprehensive review of microstructure, performance, and applications, Next Materials, 2025, vol. 9, art. 101206, DOI: 10.1016/j.nxmate.2025.101206.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Батраев И. С. Использование многокомпонентного топлива метилацетилен-алленовая фракция (МАФ) при детонационном напылении // Упрочняющие технологии и покрытия. 2017. № 1(145). С. 14—19.</mixed-citation><mixed-citation xml:lang="en">Batraev I. S. Detonation Spraying with Multi-Component Methylacetylene-Propadienepropane (MAPP) Gas Fuel, Hardening Technologies and Coatings, 2017, no. 1(145), pp. 14—19 (in Russian)</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Bao Y., Xie G., Pu P., Yao X., Jin W., Xia D.-H. Failure analysis and corrosion prediction of scratched coating/steel system in marine atmosphere using semantic segmentation and temporal prediction // Engineering Failure Analysis. 2025. Vol.181. 109912. DOI:10.1016/j.engfailanal.2025.109912.</mixed-citation><mixed-citation xml:lang="en">Bao Y., Xie G., Pu P., Yao X., Jin W., Xia D.-H. Failure analysis and corrosion prediction of scratched coating/steel system in marine atmosphere using semantic segmentation and temporal prediction, Engineering Failure Analysis, 2025, vol. 181, art. 109912, DOI:10.1016/j.engfailanal.2025.109912.</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Zhou Y., Kang J., Liu M., Ma G., Zhang Q., Zhang J., Peng Q., Gao R., Wang H. Intelligent thermal spraying: A comprehensive review of innovation driven by artificial intelligence and machine learning // Materials Today Communications. 2025. Vol. 49. Art. 113804. DOI: 10.1016/j.mtcomm.2025.113804.</mixed-citation><mixed-citation xml:lang="en">Zhou Y., Kang J., Liu M., Ma G., Zhang Q., Zhang J., Peng Q., Gao R., Wang H. Intelligent thermal spraying: A comprehensive review of innovation driven by artificial intelligence and machine learning, Materials Today Communications, 2025, vol. 49, art. 113804, DOI: 10.1016/j.mtcomm.2025.113804.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Wang S., Shen Y. CFD-DEM modelling of dense gassolid reacting flow: Recent advances and challenges // Progress in Energy and Combustion Science. 2025. Vol. 109. Art. 85. DOI:10.1016/j.pecs.2025.101221.</mixed-citation><mixed-citation xml:lang="en">Wang S., Shen Y. CFD-DEM modelling of dense gassolid reacting flow: Recent advances and challenges, Progress in Energy and Combustion Science, 2025, vol. 109, art. 85, DOI: 10.1016/j.pecs.2025.101221.</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Quaye E. K., Jianfeng P., Baowei P., Qingbo L., Yi Z., Chao J., Nauman M., Ibeobi S. Advancing sustainable combustion: A comprehensive review of response surface methodology driven optimization and applications in alternative fuel combustion systems // International Journal of Hydrogen Energy. 2025. Vol. 170. Art. 151190. DOI:10.1016/j.ijhydene.2025.151190.</mixed-citation><mixed-citation xml:lang="en">Quaye E. K., Jianfeng P., Baowei P., Qingbo L., Yi Z., Chao J., Nauman M., Ibeobi S. Advancing sustainable combustion: A comprehensive review of response surface methodology driven optimization and applications in alternative fuel combustion systems, International Journal of Hydrogen Energy, 2025, vol. 170, art. 151190, DOI:10.1016/j.ijhydene.2025.151190.</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Ihme M., Tong Chung W., Ananda Mishra A. Combustion machine learning: Principles, progress and prospects // Progress in Energy and Combustion Science. 2022. Vol. 91. Art. 101010. DOI: 10.1016/j.pecs.2022.101010.</mixed-citation><mixed-citation xml:lang="en">Ihme M., Tong Chung W., Ananda Mishra A. Combustion machine learning: Principles, progress and prospects, Progress in Energy and Combustion Science, 2022, vol. 91, art. 101010. DOI: 10.1016/j.pecs.2022.101010.</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Akbarpour H., Mohajeri M., Moradi M. Investigation on the synthesis conditions at the interpore distance of nanoporous anodic aluminum oxide: A comparison of experimental study, artificial neural network, and multiple linear regression // Computational Materials Science. 2013. Vol. 79. P. 75—81. DOI: 10.1016/j.commatsci.2013.05.048.</mixed-citation><mixed-citation xml:lang="en">Akbarpour H., Mohajeri M., Moradi M. Investigation on the synthesis conditions at the interpore distance of nanoporous anodic aluminum oxide: A comparison of experimental study, artificial neural network, and multiple linear regression, Computational Materials Science, 2013, vol. 79, pp. 75—81, DOI: 10.1016/j.commatsci.2013.05.048.</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Салахова Р. К., Тихообразов А. Б., Фарафонов Д. П., Смирнова Т. Б. Особенности электролитического осаждения абразивно-износостойких покрытий на основе никеля // Труды ВИАМ. 2022. № 2(108). С. 99—110. DOI: 10.18577/2307-6046-2022-0-2-99-110.</mixed-citation><mixed-citation xml:lang="en">Salakhova R. K., Tikhoobrazov A. B., Farafonov D. P., Smirnova T. B. Features of Electrolytic Deposition of AbrasiveWear-Resistant Nickel-Based Coatings, Proceedings of VIAM, 2022, no. 2 (108), pp. 99—110, DOI: 10.18577/2307-6046-2022-0-2-99-110 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Liu M., Tan Z, Zhao Y., Wang H., Zhang S., Ma R., Jiang T., Ma Z., Zhong N., Li W. Optimization of Spray Parameters and Corrosion Properties of Plasma-Sprayed Cr2O3 Coatings Using Response Surface Methodology // Crystals. 2025. N. 15(4). Art. 377. DOI: 10.3390/cryst15040377</mixed-citation><mixed-citation xml:lang="en">Liu M., Tan Z, Zhao Y., Wang H., Zhang S., Ma R., Jiang T., Ma Z., Zhong N., Li W. Optimization of Spray Parameters and Corrosion Properties of Plasma-Sprayed Cr2O3 Coatings Using Response Surface Methodology, Crystals, 2025, no. 15 (4), art. 377, DOI: 10.3390/cryst15040377</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Hamweendo A., Popoola P., Botef I. Mathematical model for predicting process parameters in cold spray of porous Ti coatings // Mathematical Methods in Science and Engineering. 2014. P. 225—229. DOI: 10.13140/2.1.2846.1123.</mixed-citation><mixed-citation xml:lang="en">Hamweendo A., Popoola P., Botef I. Mathematical model for predicting process parameters in cold spray of porous Ti coatings, Mathematical Methods in Science and Engineering, 2014, pp. 225—229, DOI: 10.13140/2.1.2846.1123.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
